Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels-Alder Reactions
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Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels-Alder Reactions

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Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels-Alder Reactions

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Sen, Rickdeb; Gahtory, Digvijay; Escorihuela Fuentes, Jorge; Firet, Judith; Pujari, Sidharam P.; Zuilhof, Han
Aquest document és un/a article, creat/da en: 2017
Rapid and quantitative click functionalization of surfaces remains an interesting challenge in surface chemistry. In this regard, inverse electron demand Diels-Alder (IEDDA) reactions represent a promising metal‐free candidate. Herein, we reveal quantitative surface functionalization within 15 min. Furthermore, we report the comprehensive effects of substrate stereochemistry, surrounding microenvironment and substrate order on the reaction kinetics as obtained by surface‐bound mass spectrometry (DART‐HRMS).

    Sen, Rickdeb Gahtory, Digvijay Escorihuela Fuentes, Jorge Firet, Judith Pujari, Sidharam P. Zuilhof, Han 2017 Approach Matters: The Kinetics of Interfacial Inverse‐Electron Demand Diels-Alder Reactions Chemistry-A European Journal 23 53 13015 13022
https://doi.org/10.1002/chem.201703103
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