E,Z-Stereodivergent synthesis of N-tosyl α,β-dehydroamino esters via a Mukaiyama-Michael addition
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E,Z-Stereodivergent synthesis of N-tosyl α,β-dehydroamino esters via a Mukaiyama-Michael addition

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E,Z-Stereodivergent synthesis of N-tosyl α,β-dehydroamino esters via a Mukaiyama-Michael addition

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Espinosa, Miguel; García-Ortiz, Andrea; Blay Llinares, Gonzalo Perfil; Cardona Prósper, María Luz; Muñoz, M. Carmen; Pedro, José Ramón
This document is a artículoDate2016

Este documento está disponible también en : http://hdl.handle.net/10550/58239
The stereodivergent synthesis of N-tosyl α,β-dehydroamino esters via a Mukaiyama-Michael addition is reported. The reaction of silylketene acetals with N-tosylimines derived from β,γ-unsaturated α-keto esters in dichloromethane provided the corresponding (Z)-α,β-dehydroamino esters while the (E)-isomers were obtained when the reaction was carried out in the presence of 10 mol% copper(II) triflate.

    Espinosa, Miguel García-Ortiz, Andrea Blay Llinares, Gonzalo Cardona Prósper, María Luz Muñoz, M. Carmen Pedro, José Ramón 2016 E,Z-Stereodivergent synthesis of N-tosyl α,β-dehydroamino esters via a Mukaiyama-Michael addition Rsc Advances 6 15655 15659
https://doi.org/10.1039/c5ra27354d

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