Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines
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Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines

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Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines

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Estevan Estevan, Francisco; Lahuerta Peña, Pascual; Lloret Fillol, Julio; Sanau Torrecilla, Mercedes; Ubeda Picot, M Angeles; Vila Gomez, Jaume Llorenc
Aquest document és un/a article publicat, creat/da en: 2004
Enantiomerically pure dirhodium(II) complexes with ortho-metalated p-substituted aryl phosphines have been shown to be enantio- and diastereoselective in the cyclopropanation of styrene by ethyl diazoacetate. Enantioselectivities up to 91% and diastereoselectivities up to 90% are observed for ethyl cis-2-phenylcyclopropanecarboxylate.

    ESTEVAN ESTEVAN, Francisco ; Lahuerta Peña, Pascual ; Lloret Fillol, Julio ; Sanau Torrecilla, Mercedes ; Ubeda Picot, M Angeles ; Vila Gomez, Jaume Llorenc, 2004, Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines, Chemical communications, vol. 2004, p. 2408-2409
http://www.rsc.org/ej/CC/2004/b408856e.pdf
distribuït sota llicència Creative Commons de Reconeixement-NoComercial 3.0 No adaptada

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