Manganese(iv) oxamato-catalyzed oxidation of secondary alcohols to ketones by dioxygen and pivalaldehyde
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Manganese(iv) oxamato-catalyzed oxidation of secondary alcohols to ketones by dioxygen and pivalaldehyde

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Manganese(iv) oxamato-catalyzed oxidation of secondary alcohols to ketones by dioxygen and pivalaldehyde

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Ruiz Garcia, Rafael; Aukauloo, Ally; Journaux, Yves; Fernández Picot, Isabel; Pedro, José Ramón; Rosello Arce, Antonio Luis; Cervera, Beatriz; Castro Bleda, Isabel; Muñoz, M. Carmen
Aquest document és un/a article publicat, creat/da en: 1998
A new manganese(IV) oxamato complex possessing a bis(moxo) dimanganese core has been synthesized, magnetically and structurally characterized, and found to catalyze the aerobic oxidation of secondary alcohols to ketones with cooxidation of pivalaldehyde to pivalic acid with good yields and high selectivities.

    RUIZ GARCIA, Rafael ; Aukauloo, Ally ; Journaux, Yves ; Fernandez Picot, Isabel ; Pedro Llinares, Jose Ramon ; Rosello Arce, Antonio Luis ; Cervera, Beatriz ; Castro Bleda, Isabel ; Muñoz, M. Carmen, 1998, Manganese(iv) oxamato-catalyzed oxidation of secondary alcohols to ketones by dioxygen and pivalaldehyde, Chemical communications, vol. 1998, p. 989-990
http://www.rsc.org/delivery/_ArticleLinking/DisplayArticleForFree.cfm?doi=a800930i&JournalCode=CC
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