A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone
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A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone

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A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone

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Tong, Ming-Liang; Monfort, Monserrat; Clemente Juan, Juan Modesto; Chen, Xiao-Ming; Ohba, Masaaki; Kitagawa, Susumu
Aquest document és un/a article publicat, creat/da en: 2005
Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(m1,1-N3)]6 circles in the discrete ferromagnetically-coupled MII–azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone.

    TONG, Ming-Liang ; Monfort, Monserrat ; Clemente Juan, Juan Modesto ; Chen, Xiao-Ming ; Ohba, Masaaki ; Kitagawa, Susumu, 2005, A novel high-spin heterometallic Ni12K4 cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone, Chemical communications, vol. 2005, p. 233-235
http://www.rsc.org/ej/CC/2005/b415431b.pdf
distribuït sota llicència Creative Commons de Reconeixement-NoComercial 3.0 No adaptada

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