Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands
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Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands

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Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands

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Barberis, Mario; Lahuerta Peña, Pascual; Pérez Prieto, Julia; Sanau Torrecilla, Mercedes
Aquest document és un/a article publicat, creat/da en: 2001
(P) and (M) dirhodium(II) complexes with ortho-metalated aryl phosphines are assessed as chiral catalysts in the enantioselective cyclopropanation of styrenes by ethyl diazoacetate; enantioselectivities up to 91% and up to 87%, respectively, for cis- and trans-2-arylcyclopropanecarboxylates are observed.

    BARBERIS, Mario ; Lahuerta Peña, Pascual ; Pérez Prieto, Julia ; Sanau Torrecilla, Mercedes, 2001, Enantiocontrol in the intermolecular cyclopropanation reaction catalyzed by dirhodium(II) complexes with ortho-metalated aryl phosphine ligands, Chemical communications, vol. 2001, p. 439-440
http://www.rsc.org/ej/CC/2001/b010145c.pdf
distribuït sota llicència Creative Commons de Reconeixement-NoComercial 3.0 No adaptada

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