Pyridylcarbene formation by thermal decomposition of 7-bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine under pressure
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Pyridylcarbene formation by thermal decomposition of 7-bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine under pressure

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Pyridylcarbene formation by thermal decomposition of 7-bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine under pressure

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Abarca González, Belén; Ballesteros Campos, Rafael; Blanco, Fernando
This document is a artículo publicadoDate2007

Este documento está disponible también en : http://hdl.handle.net/10550/12890
7-Bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine 1 at 1.7 atm and 100ºC decompose to form a pyridylcarbene intermediate by nitrogen expulsion. The carbene stabilization give 2-bromo-6- vinylpyridine 2, 1-(6-bromopyridin-2-yl)ethanol 3, 1-(6-Bromopyridin-2-yl)ethanone 4, 2- bromo-6-[2-(6-bromopyridin-2-yl)-2-methyl-trans-cyclopropyl]pyridine 5, and 2-bromo-6-[2-(6- bromopyridin-2-yl)-2-methyl-cis-cyclopropyl]pyridine 6.

    ABARCA GONZALEZ, Belen ; Ballesteros Campos, Rafael ; Blanco, Fernando, 2007, Pyridylcarbene formation by thermal decomposition of 7-bromo-3-methyl-[1,2,3]triazolo[1,5-a]pyridine under pressure, Arkivoc, vol. 2007, no. IV, p. 297-303
http://www.arkat-usa.org/get-file/18979/
distribuido bajo licencia Creative Commons de Reconocimiento-NoComercial 3.0 No adaptada

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